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“The Basics”
Understanding the Behavior of Light Non-Aqueous Phase Liquids (LNAPLs) in the Subsurface
February 2005
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   Welcome. The Remediation Technologies Development Forum (RTDF) Non-Aqueous Phase Liquid (NAPL) Cleanup Alliance has prepared this course on light non-aqueous phase liquids, or LNAPLs, and their impacts in the subsurface. The Alliance is a public-private partnership supported by the U.S. Environmental Protection Agency’s (EPA) Technology Innovation and Field Services Division. Its members include representatives of the petroleum industry, consultants, and state and federal  government agencies. This training is the result of  a collaborative effort involving all Alliance members. Its concept and content have evolved over several years, building upon efforts by many, including individual researchers, members of the American Petroleum Institute (API), and EPA’s Region 4 Innovative Training Workgroup. Initial drafts of the course content were reviewed by Alliance members, EPA scientists, and state government officials who deal with remediation of LNAPL sites. This final version incorporates their advice and comments.
   This course provides a basic description of the behavior of LNAPLs (specifically, petroleum hydrocarbon liquids) in the subsurface. It helps explain what many have observed in the field for years:  As LNAPLs are removed from the subsurface, LNAPLs remaining are increasingly difficult to recover.
   The training presents the technical concepts involved in LNAPL behavior, discusses the application of these concepts to real world situations, and explores how heterogeneity and other factors affect LNAPL behavior and complicate recovery.
   This training will be particularly useful to: Regulators who evaluate work plans and recommend LNAPL remedial strategies; hydrogeologists who make quantitative predictions about LNAPL volume, migration, and recovery to support these recommendations; and anyone who needs basic information about the nature of petroleum hydrocarbons in the subsurface.